A switch to vinylogous reactivity of vinyl diazo esters for the C–H allylation of benzamides by merging cobalt and photoredox catalysis-Reference-Cited by-同舟云学术

A switch to vinylogous reactivity of vinyl diazo esters for the C–H allylation of benzamides by merging cobalt and photoredox catalysis

Published:2022 Issue:100 Volume:58 Page:13967-13970
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Khot Nandkishor Prakash¹,Deo Nitish Kumar¹,Kapur Manmohan¹^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Science Education and Research Bhopal, Bhauri, Bhopal Bypass Road, Bhopal 462066, MP, India

Abstract

Herein, a de novo vinylogous reactivity of vinyl diazo esters in the C–H bond allylation of benzamides has been developed by coalescing cobalt and photoredox catalysis via C–H activation/allyl carbene migratory insertion.

Funder

Science and Engineering Research Board

Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC05332B

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