Unraveling the mystery of “tech red” – a volatile technetium oxide-Reference-Cited by-同舟云学术

Unraveling the mystery of “tech red” – a volatile technetium oxide

Published:2018 Issue:10 Volume:54 Page:1261-1264
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Lawler K. V.¹²³⁴⁵^ORCID,Childs B. C.¹²³⁴,Czerwinski K. R.¹²³⁴,Sattelberger A. P.⁶⁷⁸⁴,Poineau F.¹²³⁴,Forster P. M.¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. University of Nevada Las Vegas

3. Las Vegas

4. USA

5. High Pressure Science and Engineering Center

6. Chemical Sciences and Engineering Division

7. Argonne National Laboratory

8. Lemont

Abstract

A molecular Tc₂O₅ species is the likely identity of a volatile oxide which has remained uncharacterized for 50+ years.

Funder

National Nuclear Security Administration

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C7CC09191E

Reference14 articles.

1. Chemistry of Technetium and Rhenium Species during Low-Level Radioactive Waste Vitrification

2. The nature of the volatile technetium species formed during vitrification of borosilicate glass

3. Technetium chemistry, oxidation states and species

4. Half-Life of the Long-LivedTc99

5. Current Status of the Thermodynamic Data for Technetium and Its Compounds and Aqueous Species

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