Experimental and computational studies on H2O-promoted, Rh-catalyzed transient-ligand-free ortho-C(sp2)–H amidation of benzaldehydes with dioxazolones-Reference-Cited by-同舟云学术

Experimental and computational studies on H2O-promoted, Rh-catalyzed transient-ligand-free ortho-C(sp2)–H amidation of benzaldehydes with dioxazolones

Published:2018 Issue:64 Volume:54 Page:8889-8892
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Ding Jun¹²³⁴⁵,Jiang Wei¹²³⁴⁵,Bai He-Yuan¹²³⁴⁵,Ding Tong-Mei¹²³⁴⁵,Gao Dafang⁶⁷⁸⁹⁵,Bao Xiaoguang⁶⁷⁸⁹⁵^ORCID,Zhang Shu-Yu¹²³⁴⁵^ORCID

Affiliation:

1. Shanghai Key Laboratory for Molecular Engineering of Chiral Drugs

2. School of Chemistry and Chemical Engineering

3. Shanghai Jiao Tong University

4. Shanghai

5. China

6. College of Chemistry

7. Chemical Engineering and Materials Science

8. Soochow University

9. Suzhou

Abstract

We develop an efficient and convenient ligand-free, rhodium-catalyzed ortho-C(sp²)–H amidation of benzaldehydes with dioxazolones using H₂O as the key promoter.

Funder

Science and Technology Commission of Shanghai Municipality

National Natural Science Foundation of China

Shanghai Education Development Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC04904A

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