The formation of a 1,4-disilabenzene and its isomerization into a disilabenzvalene derivative

Author:

Sugahara Tomohiro1234,Sasamori Takahiro5674ORCID,Tokitoh Norihiro12348ORCID

Affiliation:

1. Institute for Chemical Research

2. Kyoto University

3. Kyoto 611-0011

4. Japan

5. Graduate School of Natural Sciences

6. Nagoya City University

7. Nagoya

8. Integrated Research Consortium on Chemical Sciences

Abstract

A stable 1,4-disilabenzene was generated from the reaction of a stable disilyne with 3-hexyne.

Funder

Japan Society for the Promotion of Science

Nagoya City University

Kyoto University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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2. Reaction of a Disilyne with Internal Alkynes: Reversible [1 + 2] Cycloaddition and Formation of Strained Unsaturated Silacycles;Journal of the American Chemical Society;2024-07-03

3. What is learned in the cradle is carried to the grave;Journal of Synthetic Organic Chemistry, Japan;2024-03-01

4. Recent progress in the chemistry of heavy aromatics;Proceedings of the Japan Academy, Series B;2023-12-11

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