Tailoring the activity and selectivity of Rh/SiO2 for the selective hydrogenation of phenol by CoOx promotion-Reference-Cited by-同舟云学术

Tailoring the activity and selectivity of Rh/SiO₂ for the selective hydrogenation of phenol by CoO_x promotion

Published:2022 Issue:7 Volume:12 Page:2257-2264
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Zhang Fei¹²,Wu Chunzheng³,Wang Shuibo¹,Wang Shiwei¹,Li Tong¹,Zou Laixi²,Yu Hongbo¹^ORCID,Yin Hongfeng¹

Affiliation:

1. Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, 1219 Zhongguan West Road, Ningbo, Zhejiang 315201, P. R. China

2. School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341000, P.R. China

3. Chemistry and Materials Engineering, Zhejiang A&F University, Hangzhou, Zhejiang 311300, P.R. China

Abstract

The CoOx promoted Rh/SiO2 catalyst, with a Co/Rh ratio of 1/3, had the highest activity (i.e., a phenol conversion of 98.1%) and selectivity to cyclohexanol (i.e., 99.4%), due to the formation and maximum exposure of the active Rh–CoOx interfaces.

Funder

Natural Science Foundation of Ningbo

Ningbo Municipal Bureau of Science and Technology

National Natural Science Foundation of China

China Postdoctoral Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CY/D1CY02324A

Reference51 articles.