Stabilising fleeting intermediates of stilbene photocyclization with amino-borane functionalisation: the rare isolation of persistent dihydrophenanthrenes and their [1,5] H-shift isomers
Author:
Affiliation:
1. Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials
2. School of Chemistry
3. Beijing Institute of Technology
4. Beijing 100081
5. P. R. China
6. Department of Chemistry
7. Queen's University
8. Kingston
9. Canada
Abstract
Amino-borane functionalization is the key for isolating rare air-stable dihydrophenanthrene intermediates in stilbene photocyclization.
Funder
National Natural Science Foundation of China
Natural Sciences and Engineering Research Council of Canada
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC00560E
Reference75 articles.
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3. Asymmetric photochemical reactions in solution
4. Mechanisms of Photochemical Reactions in Solution. XXII.1 Photochemical cis-trans Isomerization
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