A new bis-phenolate mesoionic carbene ligand for early transition metal chemistry
Author:
Affiliation:
1. Universität Paderborn
2. Fakultät für Naturwissenschaften
3. Department Chemie Warburger Straße 100
4. 33098 Paderborn
5. Germany
6. Universität Duisburg-Essen
7. Fakultät für Chemie
8. 45117 Essen
Abstract
A new chelating mesoionic carbene ligand, derived from 1,2,3-triazoles, with two redox-active tert-butyl-phenolate linkers has been synthesized and explored towards its reactivity and electrochemical properties in early transition metal chemistry.
Funder
Universität Paderborn
Daimler und Benz Stiftung
Verband der Chemischen Industrie
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT03099A
Reference136 articles.
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3. 1H-1,2,3-Triazol-5-ylidenes: Readily Available Mesoionic Carbenes
4. Metal Complexes of Click-Derived Triazoles and Mesoionic Carbenes: Electron Transfer, Photochemistry, Magnetic Bistability, and Catalysis
5. Application of 1,2,3-triazolylidenes as versatile NHC-type ligands: synthesis, properties, and application in catalysis and beyond
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