A new bis-phenolate mesoionic carbene ligand for early transition metal chemistry-Reference-Cited by-同舟云学术

A new bis-phenolate mesoionic carbene ligand for early transition metal chemistry

Published:2019 Issue:39 Volume:48 Page:14611-14625
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Baltrun Marc¹²³⁴⁵,Watt Fabian A.¹²³⁴⁵,Schoch Roland¹²³⁴⁵,Wölper Christoph⁶⁷⁸⁵,Neuba Adam G.¹²³⁴⁵,Hohloch Stephan¹²³⁴⁵^ORCID

Affiliation:

1. Universität Paderborn

2. Fakultät für Naturwissenschaften

3. Department Chemie Warburger Straße 100

4. 33098 Paderborn

5. Germany

6. Universität Duisburg-Essen

7. Fakultät für Chemie

8. 45117 Essen

Abstract

A new chelating mesoionic carbene ligand, derived from 1,2,3-triazoles, with two redox-active tert-butyl-phenolate linkers has been synthesized and explored towards its reactivity and electrochemical properties in early transition metal chemistry.

Funder

Universität Paderborn

Daimler und Benz Stiftung

Verband der Chemischen Industrie

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT03099A

Reference136 articles.

1. Mesoionic and Related Less Heteroatom-Stabilized N-Heterocyclic Carbene Complexes: Synthesis, Catalysis, and Other Applications

2. Recent advances in the synthesis, structural diversity, and applications of mesoionic 1,2,3-triazol-5-ylidene metal complexes

3. 1H-1,2,3-Triazol-5-ylidenes: Readily Available Mesoionic Carbenes

4. Metal Complexes of Click-Derived Triazoles and Mesoionic Carbenes: Electron Transfer, Photochemistry, Magnetic Bistability, and Catalysis

5. Application of 1,2,3-triazolylidenes as versatile NHC-type ligands: synthesis, properties, and application in catalysis and beyond

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