Flexible bifunctional monoethylphosphonate/carboxylates of Zn(ii) and Co(ii) reinforced with DABCO co-ligand: paradigmatic structural organization with pcu topology-Reference-Cited by-同舟云学术

Flexible bifunctional monoethylphosphonate/carboxylates of Zn(ii) and Co(ii) reinforced with DABCO co-ligand: paradigmatic structural organization with pcu topology

Published:2020 Issue:17 Volume:22 Page:2933-2944
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Goldman Anna¹²³⁴,Gil-Hernández Beatriz⁵⁶⁷⁸⁹^ORCID,Millan Simon¹²³⁴,Gökpinar Serkan¹²³⁴,Heering Christian¹²³⁴,Boldog Ishtvan¹²³⁴^ORCID,Janiak Christoph¹²³⁴^ORCID

Affiliation:

1. Institut für Anorganische Chemie und Strukturchemie

2. Heinrich-Heine-Universität Düsseldorf

3. D-40204 Düsseldorf

4. Germany

5. Departamento de Química

6. Facultad de Ciencias de La Laguna, Sección Química

7. Universidad de La Laguna

8. Tenerife

9. Spain

Abstract

The prototypal [M₂(EtBCP)₂(DABCO)_0.5] MOFs, compliant with isoreticular expansion in two-dimensions, show flexibility manifested by a two-step CO₂ adsorption isotherm, which might be associated to the “lever-action” of the metal-phosphonate moieties.

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CE/D0CE00275E

Reference71 articles.

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