Coexistence of normal and inverse deuterium isotope effects in a phase-transition sequence of organic ferroelectrics

Author:

Horiuchi Sachio1234ORCID,Ishibashi Shoji5234ORCID,Kobayashi Kensuke67834,Kumai Reiji67834ORCID

Affiliation:

1. Electronics and Photonics Research Institute (ESPRIT)

2. National Institute of Advanced Industrial Science and Technology (AIST)

3. Tsukuba

4. Japan

5. Research Center for Computational Design of Advanced Functional Materials (CD-FMat)

6. Condensed Matter Research Center (CMRC) and Photon Factory

7. Institute of Materials Structure Science

8. High Energy Accelerator Research Organization (KEK)

Abstract

Deuterium substitutions of the hydrogen-bonded ferroelectrics smoothly raise the Curie point and simultaneously reduce other phase-transition temperatures by a few tens of degrees.

Funder

Japan Society for the Promotion of Science

Core Research for Evolutional Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference55 articles.

1. M. E.Lines , and A. M.Glass , Principles and Applications of Ferroelectrics and Related Materials , Oxford University Press , New York , 1977

2. Ferro- and Antiferroelectricity: Order/Disorder Versus Displacive , ed. N. S. Dalal and A. Bussmann-Holder , Springer , Berlin , 2007

3. K.Uchino , Ferroelectric Devices , Marcel Dekker , New York , 2000

4. Physics of thin-film ferroelectric oxides

5. G. A.Jeffery , An Introduction to Hydrogen Bonding , Oxford University Press , Oxford , 1997

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