C(sp<sup>3</sup>)–H cyclizations of 2-(2-vinyl)phenoxy-<i>tert</i>-anilines-Reference-Cited by-同舟云学术

C(sp³)–H cyclizations of 2-(2-vinyl)phenoxy-tert-anilines

Published:2024 Issue:24 Volume:14 Page:16784-16800
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Dunkel Petra¹^ORCID,Bogdán Dóra¹,Deme Ruth¹,Zimber Ádám¹,Ballayová Veronika¹²,Csizmadia Eszter¹,Kontra Bence¹³^ORCID,Kalydi Eszter¹,Bényei Attila⁴^ORCID,Mátyus Péter¹⁵,Mucsi Zoltán³⁶⁷^ORCID

Affiliation:

1. Department of Organic Chemistry, Semmelweis University, Hőgyes Endre utca 7, H-1092 Budapest, Hungary

2. Department of Chemical Drugs, Masaryk University, Palackého 1946/1, 612 00 Brno, Czech Republic

3. Department of Biological Chemistry, Brain Vision Center, Liliom utca 43-45, H-1094 Budapest, Hungary

4. Institute of Physical Chemistry, University of Debrecen, Egyetem tér 1, H-4010 Debrecen, Hungary

5. University of Veterinary Medicine, István utca 2, H-1078 Budapest, Hungary

6. Department of Chemistry, Femtonics Ltd, Tűzoltó utca 59, H-1094 Budapest, Hungary

7. Institute of Chemistry, University of Miskolc, Egyetem út 1, H-3515 Miskolc, Hungary

Abstract

Cyclizations of 2-(2-vinyl)phenoxy-tert-anilines under thermal conditions yield oxazonine or octahydro-dipyrroloquinoline products. The transformations can be considered as further extensions of [1,n]-H transfer and cyclization of tertiary anilines.

Funder

Nemzeti Kutatási, Fejlesztési és Innovaciós Alap

Magyar Tudományos Akadémia

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/RA/D3RA08974F

Reference69 articles.

1. C–H functionalization logic in total synthesis

2. CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

3. CH Bond Functionalization through Intramolecular Hydride Transfer

4. Inverse hydride shuttle catalysis enables the stereoselective one-step synthesis of complex frameworks

5. C–H Bond Functionalization of Amines: A Graphical Overview of Diverse Methods