Gas-phase preparation and the stability of superatomic Nb11O15−-Reference-Cited by-同舟云学术

Gas-phase preparation and the stability of superatomic Nb11O15−

Published:2021 Issue:29 Volume:23 Page:15766-15773
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Lei Xin¹²³⁴,Zhang Hanyu¹²³⁴^ORCID,Jia Yuhan¹²³⁴⁵,Luo Zhixun¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry

2. Chinese Academy of Sciences

3. Beijing

4. China

5. University of Chinese Academy of Sciences

Abstract

Concentration-dependent reactions of pure metal clusters Nb_n⁻ with dioxygen give rise to the production of highly stable Nb₁₁O₁₅⁻ with a D_5h Nb@Nb₁₀ core fully protected by 15 bridge-oxygen atoms.

Funder

National Natural Science Foundation of China

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP02128A

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