Dysprosium-based complexes with a flat pentadentate donor: a magnetic and ab initio study

Author:

Fondo Matilde12345ORCID,Corredoira-Vázquez Julio12345ORCID,García-Deibe Ana M.12345ORCID,Gómez-Coca Silvia67895ORCID,Ruiz Eliseo67895ORCID,Sanmartín-Matalobos Jesús12345ORCID

Affiliation:

1. Departamento de Química Inorgánica

2. Facultade de Química

3. Universidade de Santiago de Compostela

4. 15782 Santiago de Compostela

5. Spain

6. Departament de Química Inorgànica i Orgànica

7. and Institut de Química Teórica i Computacional

8. Universitat de Barcelona

9. 08028 Barcelona

Abstract

Hitherto unknown dysprosium(iii) complexes of a related flat N3O2 donor show ac susceptibility frequency-dependence, (Et3NH)[Dy0.09Y0.91(L)(NO3)2] being a SIM at zero field.

Funder

Ministerio de Ciencia, Innovación y Universidades

Xunta de Galicia

Generalitat de Catalunya

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference60 articles.

1. Recent advances in luminescent lanthanide based Single-Molecule Magnets

2. L. Sorace and D.Gatteschi , Electronic Structure and Magnetic Properties of Lanthanide Molecular Complexes , in Lanthanides and Actinides in Molecular Magnetism , ed. R. Layfield and M. Murugesu , John Wiley & Sons , 2015

3. Lanthanide Double-Decker Complexes Functioning as Magnets at the Single-Molecular Level

4. Exploiting single-ion anisotropy in the design of f-element single-molecule magnets

5. Low-coordinate mononuclear lanthanide complexes as molecular nanomagnets

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