A spectrophotometric study of the impact of pH and metal-to-ligand ratio on the speciation of the Pu(vi)-oxalate system

Author:

Sockwell A. Kirstin1ORCID,DiBlasi Nicole A.1,Hixon Amy E.1ORCID

Affiliation:

1. Department of Civil & Environmental Engineering & Earth Sciences, University of Notre Dame, Notre Dame, IN 46556, USA

Abstract

Two aqueous Pu(vi)-oxalate species were identified through a spectroscopic study of the Pu(vi)-oxalate system as a function of [oxalate], pH, and metal-to-ligand ratio. The formation constants for both species were calculated from this data.

Funder

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference53 articles.

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5. Dioxouranium(VI) oxalate complexes †

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