Cubane-type tungsten–iron–sulfur clusters with a nitrogen atom in the core: terminal ligand substitutions and redox behaviors

Author:

Zhang Hong-Ying1,Qiu Shu-Juan1,Yang Huan-Huan1,Wang Meng-Ting1,Yang Jie1,Wang Han-Bin1,Liu Nai-Hao1,Chen Xu-Dong12ORCID

Affiliation:

1. Jiangsu Collaborative Innovation Center of Biomedical Functional Materials and Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023, Jiangsu, China

2. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, Jiangsu, China

Abstract

Terminal ligand replacement in combination with core redox chemistry has been carried out based on a cluster comprising a [WFe3S3N] cubane core, raising the possibility of regulating the electrochemical properties of M–Fe–S clusters with core 2p atom(s).

Funder

National Natural Science Foundation of China

State Key Laboratory of Coordination Chemistry

Foundation of Jiangsu Collaborative Innovation Center of Biomedical Functional Materials

Priority Academic Program Development of Jiangsu Higher Education Institutions

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference43 articles.

1. B. S.Patil , V.Hessel , L. C.Seefeldt , D. R.Dean , B. M.Hoffman , B. J.Cook and L. J.Murray , Nitrogen Fixation , Ullmann's Encyclopedia of Industrial Chemistry , Germany , 2017 , pp. 1–21

2. Global Population and the Nitrogen Cycle

3. Structural Models for the Metal Centers in the Nitrogenase Molybdenum-Iron Protein

4. Nitrogenase MoFe-Protein at 1.16 Å Resolution: A Central Ligand in the FeMo-Cofactor

5. X-ray Emission Spectroscopy Evidences a Central Carbon in the Nitrogenase Iron-Molybdenum Cofactor

Cited by 1 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Synthesis and crystal structure of the cluster (Et4N)[(Tp*)MoFe3S33-NSiMe3)(N3)3];Acta Crystallographica Section E Crystallographic Communications;2024-05-31

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