SET-LRP of NIPAM in water via in situ reduction of Cu(ii) to Cu(0) with NaBH4-Reference-Cited by-同舟云学术

SET-LRP of NIPAM in water via in situ reduction of Cu(ii) to Cu(0) with NaBH4

Published:2016 Issue:4 Volume:7 Page:933-939
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Gavrilov Mikhail¹²³⁴,Zerk Timothy J.⁵²³⁴,Bernhardt Paul V.⁵²³⁴,Percec Virgil⁶⁷⁸⁹¹⁰,Monteiro Michael J.¹²³⁴

Affiliation:

1. Australian Institute for Bioengineering and Nanotechnology

2. The University of Queensland

3. Brisbane QLD 4072

4. Australia

5. School of Chemistry and Molecular Biosciences

6. Roy & Diana Vagelos Laboratories

7. Department of Chemistry

8. University of Pennsylvania

9. Philadelphia

10. USA

Abstract

The direct and quantitative reduction of the air-stable Cu(ii)Br₂/Me₆TREN to Cu(0) by NaBH₄ represents a new method for the aqueous single electron transfer-living radical polymerization (SET-LRP) of water soluble polymers.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2016/PY/C5PY01855B

Reference36 articles.

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2. Atom Transfer Radical Polymerization (ATRP): Current Status and Future Perspectives

3. Polymerization of Methyl Methacrylate with the Carbon Tetrachloride/Dichlorotris- (triphenylphosphine)ruthenium(II)/Methylaluminum Bis(2,6-di-tert-butylphenoxide) Initiating System: Possibility of Living Radical Polymerization

4. Aqueous Room Temperature Metal-Catalyzed Living Radical Polymerization of Vinyl Chloride

5. Ultrafast Synthesis of Ultrahigh Molar Mass Polymers by Metal-Catalyzed Living Radical Polymerization of Acrylates, Methacrylates, and Vinyl Chloride Mediated by SET at 25 °C

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