[2.2]Paracyclophane-based N-heterocyclic carbene as efficient catalyst or as ligand for copper catalyst for asymmetric α-silylation of N-tosylaldimines-Reference-Cited by-同舟云学术

[2.2]Paracyclophane-based N-heterocyclic carbene as efficient catalyst or as ligand for copper catalyst for asymmetric α-silylation of N-tosylaldimines

Published:2016 Issue:12 Volume:3 Page:1725-1737
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Chen Zhen¹²³⁴⁵,Huo Yuwen¹²³⁴,An Ping⁶²⁷⁴,Wang Xichao¹²³⁴,Song Chun⁶²⁷⁴,Ma Yudao¹²³⁴

Affiliation:

1. Department of Chemistry

2. Shandong University

3. Jinan 250100

4. P. R. China

5. School of Chemistry and Chemical Engineering

6. School of Pharmaceutical Sciences

7. Jinan 250012

Abstract

A carbene precursor plays a dual role as both an organocatalyst and as a ligand for the copper catalyst in asymmetric silylation.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/QO/C6QO00386A

Reference51 articles.

1. E. W. Colvin , Silicon in organic synthesis, Krieger Publishing Company, 1981

2. Electrophilic Substitution of Organosilicon Compounds- Applications to Organic Synthesis

3. Tilden Lecture. Some uses of silicon compounds in organic synthesis

4. S. E. Denmark and R. F.Sweis, in Metal-Catalyzed Cross-Coupling Reactions, ed. A. de Meijere and F. Diederich, Wiley-VCH Verlag GmbH, Weinheim, 2008, pp. 163–216

5. Stereochemical Control in Organic Synthesis Using Silicon-Containing Compounds

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