Phosphine-free chiral iridium catalysts for asymmetric catalytic hydrogenation of simple ketones
Author:
Affiliation:
1. Department of Chemistry
2. School of Life Sciences
3. University of Sussex
4. Brighton BN1 9QJ, UK
5. Inorganic Chemistry II
6. University of Bayreuth
7. 95440-Bayreuth, Germany
Abstract
Phosphine free iridium catalysts with simple structures show efficient enantioselectivities and activities in the asymmetric hydrogenation of simple ketones by using chiral iridium catalysts to chiral alcohols with up to 96% ee.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA04524C
Reference63 articles.
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2. R. M. Bullock , in Handbook of Homogeneous hydrogenation , ed. J. G. de Vries and C. J. Elsevier , Wiley-VCH , Weinheim , 2007 , ch. 7
3. Asymmetrische Katalyse mit hinsichtlich Struktur und Funktion gezielt entworfenen Molekülen: die chemo- und stereoselektive Hydrierung von Ketonen
4. R. Noyori and T.Ohkuma , Angew. Chem., Int. Ed. , 2001 , 40 , 40
5. Industrial-Scale Synthesis and Applications of Asymmetric Hydrogenation Catalysts
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1. Cinchona-alkaloid-derived NN ligands for ruthenium catalyzed asymmetric hydrogenation of ketones;Organic & Biomolecular Chemistry;2023
2. Organometallic Iridium Complexes of (Z)-1-Phenyl-2-(4′,4′-dimethyl-2′-oxazolin-2′-yl)-eth-1-en-1-ate: Structural Aspects, Reactivity and Applications in the Catalytic Dehydrogenation of Alkanes;Bulletin of the Chemical Society of Japan;2021-08-15
3. Iridium-Catalyzed Asymmetric Hydrogenation;Iridium Catalysts for Organic Reactions;2020
4. ChemInform Abstract: Phosphine-Free Chiral Iridium Catalysts for Asymmetric Catalytic Hydrogenation of Simple Ketones.;ChemInform;2016-08
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