Multiple glassy dynamics in dipole functionalized triphenylene-based discotic liquid crystals revealed by broadband dielectric spectroscopy and advanced calorimetry – assessment of the molecular origin

Author:

Yildirim Arda1234,Bühlmeyer Andrea5674,Hayashi Shunsuke56748,Haenle Johannes Christian5674,Sentker Kathrin910114,Krause Christina1234,Huber Patrick910114ORCID,Laschat Sabine5674ORCID,Schönhals Andreas1234ORCID

Affiliation:

1. Bundesanstalt für Materialforschung und -prüfung (BAM)

2. Unter den Eichen 87

3. 12205 Berlin

4. Germany

5. Institut für Organische Chemie

6. Universität Stuttgart

7. 70569 Stuttgart

8. Department of Applied Chemistry

9. Institut für Materialphysik und -technologie

10. Technische Universität Hamburg

11. 21073 Hamburg

Abstract

A selected series of dipole functionalized triphenylene-based discotic liquid crystals (DLCs) was synthesized and investigated in a systematic way to reveal the phase behavior and molecular dynamics.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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