Bis-(1,2,4-triazin-3-yl) ligand structure driven selectivity reversal between Am3+ and Cm3+: solvent extraction and DFT studies-Reference-Cited by-同舟云学术

Bis-(1,2,4-triazin-3-yl) ligand structure driven selectivity reversal between Am3+ and Cm3+: solvent extraction and DFT studies

Published:2021 Issue:22 Volume:50 Page:7783-7790
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bhattacharyya Arunasis¹²³⁴^ORCID,Ansari S. A.¹²³⁴^ORCID,Karthikeyan N. S.⁵⁶⁴^ORCID,Ravichandran C.⁵⁶⁴,Venkatachalapathy B.⁵⁶⁴,Rao T. S.⁷⁸⁹⁴,Seshadri H.¹⁰¹¹⁹⁴,Mohapatra P. K.¹²³⁴^ORCID

Affiliation:

1. Radiochemistry Division

2. Bhabha Atomic Research Centre

3. Mumbai – 400 085

4. India

5. Easwari Engineering College

6. Chennai – 600089

7. Water & Steam Chemistry Division

8. BARC

9. Kalpakkam – 603102

10. Safety Research Institute

11. Atomic Energy Regulatory Board

Abstract

Selectivity between Am³⁺ and Cm³⁺ reversed from a tridentate (SO₃PhBTP) to tetradentate (SO₃PhBTP or SO₃PhBTPhen) ligand which is explained using DFT calculations and exploited for the separation of Am³⁺ and Cm³⁺ using TODGA in RTIL.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00307K

Reference50 articles.

1. Minor actinide transmutation—a waste management option

2. Nuclear fuel cycle strategies including Partitioning and Transmutation

3. ACTINIDE PARTITIONING—A REVIEW

Cited by 9 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Remarkable Improvement in Am³⁺ and Cm³⁺ Separation Using a Cooperative Counter Selectivity Strategy by a Combination of Branched Diglycolamides and Hydrophilic Polyaza-heterocycles;Inorganic Chemistry;2024-06-11

2. A synthetic strategy for the preparation of alkoxy‐functionalized bis‐1,2,4‐triazinyl‐2,6‐pyridines;Journal of Heterocyclic Chemistry;2024-05-23

3. Next-Generation 3,3′-AlkoxyBTPs as Complexants for Minor Actinide Separation from Lanthanides: A Comprehensive Separations, Spectroscopic, and DFT Study;Inorganic Chemistry;2024-03-04

4. First Report on a 1-Cycle Solid-Phase Extraction Method for Selective Separation of Am³⁺ and Eu³⁺: Use of BTP-Grafted Silica Decorated on Activated Carbon;Industrial & Engineering Chemistry Research;2024-02-06

5. Computational Tools and Techniques in Designing Ligands for the Selective Separation of Actinide and Lanthanide: A Review;Comments on Inorganic Chemistry;2024-01-29