Controlling the diversity of ion-induced fragmentation pathways by N-methylation of amino acids

Author:

Barreiro-Lage Darío1ORCID,Nicolafrancesco Chiara23,Kočišek Jaroslav4ORCID,Luna Alberto5,Kopyra Janina6ORCID,Alcamí Manuel178ORCID,Huber Bernd A.2,Martín Fernando179ORCID,Domaracka Alicja2ORCID,Rousseau Patrick2ORCID,Díaz-Tendero Sergio189ORCID

Affiliation:

1. Departamento de Química, Módulo 13, Universidad Autónoma de Madrid, Madrid 28049, Spain

2. Normandie Univ, ENSICAEN, UNICAEN, CEA, CNRS, CIMAP, Caen 14000, France

3. Synchrotron SOLEIL, LOrme des Merisiers, St Aubin, BP 48, Gif sur Yvette Cedex 91192, France

4. J. Heyrovsky Institute of Physical Chemistry v.v.i., The Czech Academy of Sciences, Dolejskova 3, Prague 18223, Czech Republic

5. Centro de Computación Científica, Universidad Autónoma de Madrid, Madrid 28049, Spain

6. Faculty of Exact and Natural Sciences, Siedlce University of Natural Sciences and Humanities, 3 Maja 54, Siedlce 08-110, Poland

7. Instituto Madrileño de Estudios Avanzados en Nanociencia (IMDEA-Nano), Campus de Cantoblanco, Madrid 28049, Spain

8. Institute for Advanced Research in Chemical Sciences (IAdChem), Universidad Autónoma de Madrid, Madrid 28049, Spain

9. Condensed Matter Physics Center (IFIMAC), Universidad Autónoma de Madrid, Madrid 28049, Spain

Abstract

In a joint experimental and theoretical study, we report on the fragmentation of singly and doubly N-methylated glycine induced by low-energy (keV) O6+ ions.

Funder

European Cooperation in Science and Technology

Institut National de la Santé et de la Recherche Médicale

Ministerio de Ciencia e Innovación

Centre National de la Recherche Scientifique

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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