Ionic-liquid-based synthesis of tellurium–rhenium carbonyls with specific reaction control
Author:
Affiliation:
1. Institute of Inorganic Chemistry
2. Karlsruhe Institute of Technology (KIT)
3. 76131 Karlsruhe
4. Germany
Abstract
The novel tellurium rhenium carbonyls [TeI2Re(CO)5][AlCl4] (1), [BMIm][Te2I4(μ-I)2Re(CO)4] (2), {Te3I2(μ-I)3(μ3-I)}Re(CO)3 (3) and [BMIm][(Te2)3{Re(CO)3}2{Re(CO)4}3] (4) were prepared by reacting TeI4 and Re2(CO)10 in ionic liquids (ILs).
Funder
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT01897B
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4. Controlled Synthesis of Polyions of Heavy Main-Group Elements in Ionic Liquids
5. A guest-free germanium clathrate
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