Theoretical study of direct internal protonation of a [1.1.1]cryptand by proton carriers-Reference-Cited by-同舟云学术

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Theoretical study of direct internal protonation of a [1.1.1]cryptand by proton carriers

Published:2024 Issue:26 Volume:48 Page:12015-12024
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Ishikawa Shigeru¹^ORCID

Affiliation:

1. Department of Chemistry, School of Science, Tokai University, 4-1-1 Kitakaname, Hiratsuka 259-1292, Japan

Abstract

The use of a strongly basic proton carrier (e.g. ammonia) inhibits the external protonation of [1.1.1]cryptand amines and allows rapid internal protonation without the use of strong acids.

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/NJ/D4NJ01424C

Reference14 articles.

1. J.-M.Lehn , Supramolecular Chemistry , VCH , Weinheim , 1995

2. Proton cryptates

3. Proton cryptates. Kinetics and thermodynamics of protonation of the [1.1.1] macrobicyclic cryptand

4. Wolfram Research, Inc., Mathematica, Version 13.1, Champaign, IL, 2022

5. [1.1.1]Cryptand: directions for its use as a variable-pH kinetic molecular device

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