Facile formation of tetrazole–thiolato Pd(<scp>ii</scp>) and Pt(<scp>ii</scp>) complexes through deprotonation or oxidative addition using organic tetrazole

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Facile formation of tetrazole–thiolato Pd(ii) and Pt(ii) complexes through deprotonation or oxidative addition using organic tetrazole–thiones

Published:2024 Issue:30 Volume:48 Page:13358-13372
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Kwon Hyoung Soon¹,Park Geon Hyeong¹,Ju Huiyeong²^ORCID,Lee Eunji¹^ORCID,Kim Yong-Joo¹^ORCID

Affiliation:

1. Department of Chemistry, Gangneung-Wonju National University, Gangneung 25457, Korea

2. Western Seoul Center, Korea Basic Science Institute, Seoul 03759, Korea

Abstract

Reactions of M(ii) and M(0) (M = Pd, Pt) complexes with organic tetrazole–thiones afford corresponding various mono or bis(tetrazole–thiolato) M(ii) and unusual cyclometallated M(ii) complexes via deprotonation or oxidative addition.

Funder

Ministry of Education, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/NJ/D4NJ01429D

Reference66 articles.

1. Azide Chemistry - An Inorganic Perspective, Part II[‡][3+2]-Cycloaddition Reactions of Metal Azides and Related Systems

2. Platinum and palladium complexes with tetrazole ligands: Synthesis, structure and applications

3. Metallophilic Bonding and Agostic Interactions in Gold(I) and Silver(I) Complexes Bearing a Thiotetrazole Unit

4. Tetrazole derivatives as corrosion inhibitors for copper in chloride solutions

5. Corrosion inhibition of iron in 1M HCl by 1-phenyl-5-mercapto-1,2,3,4-tetrazole

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