A bio-inspired design and computational prediction of scorpion-like SCS nickel pincer complexes for lactate racemization-Reference-Cited by-同舟云学术

A bio-inspired design and computational prediction of scorpion-like SCS nickel pincer complexes for lactate racemization

Published:2017 Issue:83 Volume:53 Page:11410-11413
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Qiu Bing¹²³⁴⁵^ORCID,Yang Xinzheng¹²³⁴⁵^ORCID

Affiliation:

1. Beijing National Laboratory for Molecular Sciences

2. State Key Laboratory for Structural Chemistry of Unstable and Stable Species

3. CAS Research/Education Center for Excellence in Molecular Sciences

4. Institute of Chemistry

5. Chinese Academy of Sciences

Abstract

Computationally predicted scorpion-like SCS nickel pincer complexes are promising for the catalysis of lactate racemization under mild conditions.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C7CC06416K

Reference16 articles.

1. Lactate Racemization as a Rescue Pathway for Supplying d -Lactate to the Cell Wall Biosynthesis Machinery in Lactobacillus plantarum

2. Lactate racemase is a nickel-dependent enzyme activated by a widespread maturation system

3. A tethered niacin-derived pincer complex with a nickel-carbon bond in lactate racemase

4. Nickel-pincer cofactor biosynthesis involves LarB-catalyzed pyridinium carboxylation and LarE-dependent sacrificial sulfur insertion

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