Theoretical studies on the spin trapping of the 2-chloro-5-hydroxy-1,4-benzoquinone radical by 5,5-dimethyl-1-pyrroline N-oxide (DMPO): the identification of the C–O bonding spin adduct

Author:

Feng Wenling12345,Ren Cong12345,Wang Weihua12345,Guo Chao12345,Sun Qiao67895,Li Ping12345

Affiliation:

1. Key Laboratory of Life-Organic Analysis

2. School of Chemistry and Chemical Engineering

3. Qufu Normal University

4. Qufu

5. P. R. China

6. Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions

7. School for Radiological and Interdisciplinary Sciences

8. Soochow University

9. Suzhou

Abstract

The C–O bonding spin adduct has been identified in the spin trapping of 2-chloro-5-hydroxy-1,4-benzoquinone radical by DMPO.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference41 articles.

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2. Stockholm Convention, Countries move forward on important issues for sustainable management of chemicals and waste, Geneva, 2015, http://chm.pops.int/Home/tabid/2121/Default.aspx

3. Role of Quinones in Toxicology

4. Nonenzymatic displacement of chlorine and formation of free radicals upon the reaction of glutathione with PCB quinones

5. Catalytic Degradation of Chlorinated Phenols

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