Ground and excited states analysis of alkali metal ethylenediamine and crown ether complexes-Reference-Cited by-同舟云学术

Ground and excited states analysis of alkali metal ethylenediamine and crown ether complexes

Published:2021 Issue:36 Volume:23 Page:20298-20306
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Ariyarathna Isuru R.¹^ORCID,Miliordos Evangelos¹^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, Auburn University, Auburn, AL 36849-5312, USA

Abstract

Quantum calculations show that ethylenediamine and crown ethers polarize and displace valence electrons of alkali metals to the periphery of the formed complex. The nature of the building blocks of expanded metals and electrides is discussed.

Funder

National Science Foundation

U.S. Department of Energy

Auburn University

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP02552J

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