Denovo asymmetric synthesis of the mezzettiaside family of natural products via the iterative use of a dual B-/Pd-catalyzed glycosylation
Author:
Affiliation:
1. Department of Chemistry and Chemical Biology
2. Northeastern University
3. Boston, USA
4. Department of Chemistry
5. West Virginia University
6. Morgantown, USA
Abstract
Synthesis of the mezzettiaside family of natural products via the iterative use of a dual nucleophilic boron/electrophilic Pd-catalyzed glycosylation.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/SC/C4SC00593G
Reference37 articles.
1. Chemistry of the annonaceae, Part 29. Structure of mezzettiaside-2, -4, -5, -6 and -7, new partially esterified 1-O-octyl tri- and tetra-rhamnosyl derivatives from Mezzettia leptopoda
2. Structural characterization, by two-dimensional NMR spectroscopy and fast-atom-bombardment mass spectrometry, of a highly acylated trirhamnoside from Mezzettialeptopoda (Annonaceae)
3. Novel Cytotoxic Acylated Oligorhamnosides from Mezzettia leptopoda
4. Structure–Activity Relationship Study of the Cleistriosides and Cleistetrosides for Antibacterial/Anticancer Activity
5. Synthesis of Several Cleistrioside and Cleistetroside Natural Products via a Divergent De Novo Asymmetric Approach
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