Selective methane electrosynthesis enabled by a hydrophobic carbon coated copper core–shell architecture

Author:

Zhang Xin Yu1,Li Wen Jing1,Wu Xue Feng1,Liu Yuan Wei1,Chen Jiacheng2,Zhu Minhui2ORCID,Yuan Hai Yang1ORCID,Dai Sheng3ORCID,Wang Hai Feng4ORCID,Jiang Zheng5ORCID,Liu Peng Fei1ORCID,Yang Hua Gui1ORCID

Affiliation:

1. Key Laboratory for Ultrafine Materials of Ministry of Education, Shanghai Engineering Research Center of Hierarchical Nanomaterials, School of Materials Science and Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai, 200237, China

2. State Key Laboratory of Chemical Engineering, School of Chemical Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, China

3. Key Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center, Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai, 200237, China

4. Key Laboratory for Advanced Materials, Centre for Computational Chemistry and Research Institute of Industrial Catalysis, School of Chemistry and Molecular Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai, 200237, China

5. Shanghai Synchrotron Radiation Facility, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 239 Zhangheng Road, Shanghai, 201204, China

Abstract

A hydrophobic core–shell architecture was constructed to control local H2O availability on the surface of the copper-based materials, which could provide a maximum generation rate of −434 mA cm−2 towards CH4.

Funder

China National Funds for Distinguished Young Scientists

National Natural Science Foundation of China

Shanghai Municipal Education Commission

Fundamental Research Funds for the Central Universities

Shanghai Rising-Star Program

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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