PtAg<sub>18</sub> superatoms costabilized by phosphines and halides: synthesis, structure, and catalysis-Reference-Cited by-同舟云学术

PtAg₁₈ superatoms costabilized by phosphines and halides: synthesis, structure, and catalysis

Published:2023 Issue:44 Volume:15 Page:17818-17824
ISSN:2040-3364
Container-title:Nanoscale
language:en
Short-container-title:Nanoscale

Author:

Wang Meng¹²,Wang Lin¹,Wu Haoyuan¹,Sun Jing¹,Xu Xiaoxuan¹,Guo Shuo²^ORCID,Jia Yanyuan²³,Li Simin¹,Guan Zong-Jie⁴,Shen Hui¹^ORCID

Affiliation:

1. College of Energy Materials and Chemistry, Inner Mongolia University, Hohhot 010021, China

2. College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, China

3. Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin, 300071, China

4. College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China

Abstract

An 8-electron [PtAg18(dppp)6Cl8](SbF6)2 superatom has been synthesized and its molecular structure determined. The presence of surface open sites endows the cluster with high catalytic activity in hydrogenation reactions.

Funder

Inner Mongolia University

Natural Science Foundation of Inner Mongolia

Research Program of Science and Technology at Universities of Inner Mongolia Autonomous Region

Inner Mongolia University of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

Link

http://pubs.rsc.org/en/content/articlepdf/2023/NR/D3NR02196C

Reference80 articles.

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