Non-centrosymmetric sulfides A2Ba6MnSn4S16 (A = Li, Ag): syntheses, structures and properties-Reference-Cited by-同舟云学术

Non-centrosymmetric sulfides A2Ba6MnSn4S16 (A = Li, Ag): syntheses, structures and properties

Published:2020 Issue:18 Volume:49 Page:5914-5920
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Duan Ruihuan¹²³⁴⁵^ORCID,Lin Hua⁵⁶⁷⁸⁹^ORCID,Wang Yue¹⁰¹¹¹²⁴^ORCID,Zhou Yuqiao¹³¹⁴¹⁵¹⁶¹⁷^ORCID,Wu Liming⁵⁶⁷⁸⁹^ORCID

Affiliation:

1. College of Chemistry and Chemical Engineering

2. Xinyang Normal University

3. Xinyang 464000

4. China

5. State Key Laboratory of Structural Chemistry

6. Fujian Institute of Research on the Structure of Matter

7. Chinese Academy of Sciences

8. Fuzhou

9. People's Republic of China

10. School of Biological and Chemical Engineering

11. Chongqing University of Education

12. Chongqing 400067

13. Key Laboratory of Green Chemistry & Technology

14. Ministry of Education

15. College of Chemistry

16. Sichuan University

17. Chengdu 610064

Abstract

Li₂Ba₆MnSn₄S₁₆ and Ag₂Ba₆MnSn₄S₁₆ are synthesized for the first time. By modulating disordered sites with Mn²⁺, they not only show strong SHG responses and wide band gaps (5.1, 2.7 × AgGaS₂; 2.88, 2.76 eV), but also possess paramagnetism.