Affiliation:
1. Theoretical and Computational Chemistry Laboratory, School of Chemistry, Bharathidasan University, Tiruchirappalli 620024, India
Abstract
NiIII and NiIV-center complexes prefer direct reductive elimination than reacting through five-coordinate intermediates. 32+ complex in the presence of Cl− undergoes Cl–Csp2 elimination preferably over Cl–Csp3 and Csp3–Csp2 elimination.
Funder
Council of Scientific and Industrial Research, India
Department of Science and Technology, Ministry of Science and Technology, India
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Cited by
3 articles.
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