Well-defined amine-reactive polymethacrylates through organocatalyzed controlled radical polymerization

Author:

Ho Hien The1ORCID,Montembault Véronique2ORCID,Pascual Sagrario2ORCID,Fontaine Laurent2ORCID,Gigmes Didier1ORCID,Phan Trang N. T.1ORCID

Affiliation:

1. Aix Marseille Univ, CNRS, Institut de Chimie Radicalaire UMR 7273, Marseille, France

2. Institut des Molécules et Matériaux du Mans (IMMM) UMR 6283 CNRS– Le Mans Université, Av. O. Messiaen, 72085 Le Mans cedex 9, France

Abstract

A novel alkyl iodide bearing an azlactone group was successfully employed as a reversible complex-mediated polymerization (RCMP) initiator for synthesizing for the first-time well-defined α-azlactone-terminated polymethacrylates (Đ < 1.30). The amine-scavenging ability of the resulting functional polymers was demonstrated by using benzylamine.

Funder

Aix-Marseille Université

Centre National de la Recherche Scientifique

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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