Thermodynamics of N–H bond formation in bis(phosphine) molybdenum(ii) diazenides and the influence of the trans ligand-Reference-Cited by-同舟云学术

Thermodynamics of N–H bond formation in bis(phosphine) molybdenum(ii) diazenides and the influence of the trans ligand

Published:2016 Issue:40 Volume:45 Page:15922-15930
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bezdek Máté J.¹²³⁴,Chirik Paul J.¹²³⁴

Affiliation:

1. Department of Chemistry

2. Princeton University

3. Princeton

4. USA

Abstract

Dinitrogen-derived molybdenum alkyldiazenides and alkylhydrazides were synthesized with various trans ligands. The thermodynamics of N–H bond formation were studied both experimentally and computationally.

Funder

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT01932C

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