Hot water-promoted cyclopropylcarbinyl rearrangement facilitates construction of homoallylic alcohols
Author:
Affiliation:
1. State Key Laboratory and Institute of Elemento-Organic Chemistry
2. Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)
3. Nankai University
4. Tianjin
5. China
Abstract
Hot water can promote the rearrangements of various types of cyclopropyl carbinols to afford acyclic or cyclic homoallylic alcohols in high yields.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/OB/C5OB00305A
Reference67 articles.
1. Selective reactions using allylic metals
2. Diastereoselective Reactions of Chiral Allyl and Allenyl Silanes with Activated C:X .pi.-Bonds
3. Catalytic Enantioselective Addition of Allylic Organometallic Reagents to Aldehydes and Ketones
4. The Domino Multicomponent Allylation Reaction for the Stereoselective Synthesis of Homoallylic Alcohols
5. Diastereoselective Allylation of Carbonyl Compounds and Imines: Application to the Synthesis of Natural Products
Cited by 15 articles. 订阅此论文施引文献 订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. Stereoselective Synthesis of Highly Functionalized Cyclohexenes via Strong-Acid-Mediated Endocyclic C–C Bond Cleavage of Monocyclopropanated Cyclopentadienes;Organic Letters;2023-05-30
2. Photoexcited Palladium-Initiated Remote Desaturation of N-Alkoxypyridinium Salts;The Journal of Organic Chemistry;2022-10-11
3. Ca(NTf 2 ) 2 /HFIP‐Mediated Direct and Mild Rearrangement of Cyclopropyl Carbinols to E ‐Homoallylic Triflimides;European Journal of Organic Chemistry;2022-09-22
4. Brookhart's Acid‐Catalyzed Switchable Regioselective N ‐Alkylation of Arylamines/Heterocyclic Amines with Cyclopropylcarbinols by Temperature Regulation;Chemistry – A European Journal;2022-09-16
5. Rapid Access to Arylated and Allylated Cyclopropanes via Brønsted Acid-Catalyzed Dehydrative Coupling of Cyclopropylcarbinols;The Journal of Organic Chemistry;2022-05-10
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线，采集、加工和组织学术论文而形成的新型学术文献查询和分析系统，可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容，当前同舟云学术共收录了国内外主流学术期刊6万余种，收集的期刊论文及会议论文总量共计约1.5亿篇，并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询！咨询电话：010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3