Conversion of carbon dioxide to a novel molecule NCNBO− mediated by NbBN2− anions at room temperature

Author:

Chu Lan-Ye1,Wang Ming1,Ma Jia-Bi1ORCID

Affiliation:

1. Key Laboratory of Cluster Science of Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 102488, China

Abstract

Thermal activation of CO2 by NbBN2 anions is studied experimentally and theoretically, and novel molecules are formed, in which two CO double bonds in one CO2 molecule are completely broken and two C–N bonds are formed in the product NCNBO.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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