Alkyl chain regulation: distinctive odd–even effects of mechano-luminescence and room-temperature phosphorescence in alkyl substituted carbazole amide derivatives

Author:

Tu Liangjing1,Che Weilong1,Li Shuhui1,Li Xiaoning1,Xie Yujun12ORCID,Li Zhen134ORCID

Affiliation:

1. Institute of Molecular Aggregation Science, Tianjin University, Tianjin 300072, China

2. Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates (South China University of Technology), Guangzhou 510640, China

3. Department of Chemistry, Wuhan University, Wuhan, Hubei 430072, China

4. Joint School of National University of Singapore and Tianjin University, International Campus of Tianjin University Binhai New City, Fuzhou, Fujian 350207, China

Abstract

A series of carbazole amide derivatives with different lengths from methyl to octyl (CAC-N, N = 1–8). Compounds with even-numbered alkyl chains exhibit mechanoluminescence (ML) property, however, no ML is observed in the odd-numbered counterparts.

Funder

National Natural Science Foundation of China

South China University of Technology

Tianjin University

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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