Dynamical evolution of the Schottky barrier as a determinant contribution to electron–hole pair stabilization and photocatalysis of plasmon-induced hot carriers

Author:

Berdakin Matias12ORCID,Soldano German12ORCID,Bonafé Franco P.3ORCID,Liubov Varlamova4,Aradi Bálint4ORCID,Frauenheim Thomas45,Sánchez Cristián G.6ORCID

Affiliation:

1. INFIQC (CONICET-UNC), Ciudad Universitaria, Pabellón Argentina, 5000 Córdoba, Argentina

2. Departamento de Química Teórica y Computacional, Fac. de Ciencias Químicas, Universidad Nacional de Córdoba, Ciudad Universitaria, Pabellón Argentina, X5000HUA Córdoba, Argentina

3. Max Planck Institute for the Structure and Dynamics of Matter, Center for Free Electron Laser Science, Hamburg, Germany

4. Bremen Center for Computational Materials Science, Universitát Bremen, Bremen, Germany

5. Computational Science Research Center (CSRC) Beijing and Computational Science and Applied Research (CSAR) Institute, Shenzhen, China

6. Instituto Interdisciplinario de Ciencias Básicas, Facultad de Ciencias Exactas y Naturales, Universidad Nacional de Cuyo, CONICET, Padre Jorge Contreras 1300, Mendoza M5502JMA, Argentina

Abstract

We describe a photo-induced dynamic contribution to carrier separation stabilization in the Au-TiO2 system and its effects in the photocatalysis triggered by hot carriers.

Funder

Consejo Nacional de Investigaciones Científicas y Técnicas

Secretaria de Ciencia y Tecnología - Universidad Nacional de Córdoba

H2020 Marie Skłodowska-Curie Actions

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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