(Iminophosphoranyl)(thiophosphoranyl)methane rare-earth borohydride complexes: synthesis, structures and polymerization catalysis-Reference-Cited by-同舟云学术

(Iminophosphoranyl)(thiophosphoranyl)methane rare-earth borohydride complexes: synthesis, structures and polymerization catalysis

Published:2015 Issue:27 Volume:44 Page:12338-12348
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Schmid Matthias¹²³⁴⁵,Oña-Burgos Pascual¹²³⁴⁶,Guillaume Sophie M.⁵⁷⁸⁹¹⁰,Roesky Peter W.¹²³⁴

Affiliation:

1. Institut für Anorganische Chemie

2. Karlsruher Institut für Technologie (KIT)

3. 76131 Karlsruhe

4. Germany

5. Institut des Sciences Chimiques de Rennes

6. Department of Chemistry and Physics

7. CNRS - Université de Rennes 1 (UMR 6226)

8. Organometallics

9. Materials and Catalysis

10. Campus de Beaulieu

Abstract

The {CH(PPh₂NSiMe₃)(PPh₂S)}⁻ligand has been used for the synthesis of divalent and trivalent rare-earth borohydride complexes. These compounds enable the ring-opening polymerization (ROP) of ε-caprolactone (CL) and trimethylene carbonate (TMC).

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT04034A

Reference82 articles.

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3. [Ph2P(NSiMe3)]2CLi2: A Dilithium Dianionic Methanide Salt with an Unusual Li4C2 Cluster Structure

4. Magnesium Complexes of Bis(phosphinimine)methane and -methanide Ligands

5. Bis(phosphinimino)methanides as ligands in divalent lanthanide and alkaline earth chemistry – synthesis, structure, and catalysis

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