Origin of ligand effects on reactivities of pincer-Pd catalyzed hydrocarboxylation of allenes and alkenes with formate salts: a computational study-Reference-Cited by-同舟云学术

Origin of ligand effects on reactivities of pincer-Pd catalyzed hydrocarboxylation of allenes and alkenes with formate salts: a computational study

Published:2018 Issue:11 Volume:8 Page:2835-2840
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Lv Xiangying¹²³⁴⁵,Huang Fang⁶⁷⁸⁹^ORCID,Wu Yan-Bo¹⁰¹¹¹²¹³⁹^ORCID,Lu Gang¹⁴¹⁵¹⁶¹⁷^ORCID

Affiliation:

1. Key Laboratory for Yellow River and Huai River Water Environment and Pollution Control

2. Ministry of Education

3. Henan Key Laboratory for Environmental Pollution Control

4. School of Environment

5. Henan Normal University

6. College of Chemistry, Chemical Engineering and Materials Science

7. Shandong Normal University

8. Jinan 250014

9. P. R. China

10. Key Lab for Materials of Energy Conversion and Storage of Shanxi Province and Key Lab of Chemical Biology and Molecular Engineering of Ministry of Education

11. Institute of Molecular Science

12. Shanxi University

13. Taiyuan

14. Department of Chemistry

15. University of Pittsburgh

16. Pittsburgh

17. USA

Abstract

Distortion induced by R substituents on PGeP-pincer ligands is the key factor affecting the reactivity of CO₂ insertion into allylpalladium and benzylpalladium intermediates.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CY/C8CY00405F

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