Ph3P-mediated highly selective C(α)–P coupling of quinone monoacetals with R2P(O)H: convenient and practical synthesis of ortho-phosphinyl phenols
Author:
Affiliation:
1. State Key Laboratory of Materials-Oriented Chemical Engineering
2. College of Chemical Engineering
3. Nanjing Tech University
4. Nanjing 210009
5. China
6. National Institute of Advanced Industrial Science & Technology (AIST)
7. Tsukuba
8. Japan
Abstract
The Ph3P-mediated C(α)–P coupling reaction of quinone monoacetals with secondary phosphine oxides is developed to provide an effective method for the synthesis of a wide array of ortho-phosphinyl phenols in good to excellent yields.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Jiangsu Province
Nanjing Tech University
Publisher
Royal Society of Chemistry (RSC)
Subject
Pollution,Environmental Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/GC/C8GC02918K
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