Shape-selective one-step synthesis of branched gold nanoparticles on the crystal surface of redox-active PdII-macrocycles

Author:

Yamashita Yutaro1ORCID,Tashiro Shohei1ORCID,Ishii Yoshiki2,Uchihashi Takayuki2ORCID,Matsushita Nobuyuki3ORCID,Kubota Ryou1ORCID,Shionoya Mitsuhiko1ORCID

Affiliation:

1. Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan

2. Department of Physics, Structural Biology Research Center, Graduate School of Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi 464-8602, Japan

3. Department of Chemistry, College of Science and Research Center for Smart Molecules, Rikkyo University, Nishi-Ikebukuro, Toshima-ku, Tokyo 171-8501, Japan

Abstract

Redox-active PdII3-macrocycle crystals were found to provide an excellent platform for gold reduction and growth of immobilized particles, leading to the one-step synthesis of stable, monodisperse, Konpeito-shaped gold nanoparticles.

Funder

Japan Society for the Promotion of Science

Tanaka Memorial Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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