Extending the π-conjugation system of covalent organic frameworks for more efficient photocatalytic H2O2 production

Author:

Deng Maojun1,Sun Jiamin1,Laemont Andreas1,Liu Chunhui1ORCID,Wang Linyang1,Bourda Laurens12ORCID,Chakraborty Jeet1,Van Hecke Kristof2ORCID,Morent Rino3,De Geyter Nathalie3ORCID,Leus Karen13ORCID,Chen Hui1,Van Der Voort Pascal1ORCID

Affiliation:

1. COMOC-Center for Ordered Materials, Organometallics and Catalysis, Department of Chemistry, Ghent University, Krijgslaan 281-S3, 9000 Ghent, Belgium

2. XStruct, Department of Chemistry, Ghent University, Krijgslaan 281-S3, 9000 Ghent, Belgium

3. RUPT-Research Unit Plasma Technology, Department of Applied Physics, Ghent University, Sint-Pietersnieuwstraat 41 B4, 9000 Gent, Belgium

Abstract

Three highly crystalline and porous COFs with promising photoredox properties have been prepared. Via a post-sulfurization process, the imine-linked COFs were converted into thiazole-linked COFs, generating a highly conjugated and ultrastable photocatalyst for H2O2 production.

Funder

China Scholarship Council

Universiteit Gent

Fonds Wetenschappelijk Onderzoek

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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