Chiral (phosphine)-(imidazoline) PCN pincer palladium(<scp>ii</scp>) complexes: synthesis and application in asymmetric hydrophosphination of 2-alkenoylpyridines with diphenylphosphine-Reference-Cited by-同舟云学术

Chiral (phosphine)-(imidazoline) PCN pincer palladium(ii) complexes: synthesis and application in asymmetric hydrophosphination of 2-alkenoylpyridines with diphenylphosphine

Published:2022 Issue:21 Volume:51 Page:8350-8367
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Huang Jun-Jian¹,Zhang Xiao-Qi¹,Yang Jing-Jing¹,Gong Jun-Fang¹^ORCID,Song Mao-Ping¹^ORCID

Affiliation:

1. College of Chemistry, Green Catalysis Center, Zhengzhou University, Zhengzhou 450001, China

Abstract

Twelve new chiral PCN pincer Pd(ii) complexes with varied chiral imidazoline moieties have been synthesized, structurally characterized and used as catalysts for enantioselective hydrophosphination of 2-alkenoylpyridines with diphenylphosphine.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT01078J

Reference61 articles.

1. Enantioselective Reaction Using Palladium Pincer Complexes with C₂-Symmetric Chiral Bis(imidazoline)s

2. Chiral palladium pincer complexes for asymmetric catalytic reactions

3. Organometallic chemistry and application of palladacycles in asymmetric hydrophosphination reactions