A general and selective Ni-catalysed reductive amination using hydrazine hydrate as facile hydrogen and nitrogen sources-Reference-Cited by-同舟云学术

A general and selective Ni-catalysed reductive amination using hydrazine hydrate as facile hydrogen and nitrogen sources

Published:2023 Issue:23 Volume:47 Page:11318-11324
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Zhu Jiazheng¹,Duan Chengjie¹,Ye Sen²^ORCID,Zhang Qizhong³,Li Kun¹,He Guangke¹^ORCID,Liu Xiang¹⁴^ORCID,Zhang Zhiguo⁵⁴^ORCID

Affiliation:

1. School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China

2. Morningside Laboratory for Chemical Biology and Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, China

3. Anhui Haihua Chemical Technology Group Co., Ltd, Bengbu 233000, China

4. Institute of Zhejiang University-Quzhou, Quzhou 32400, China

5. Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, 38 Zheda Road, Hangzhou 310027, China

Abstract

Robust Ni-catalysed reductive amination of aldehydes/ketones with hydrazine hydrate yields primary amines (up to 99%). Enhanced reactivity and selectivity due to high Ni0 ratio, small-sized Ni nanoparticles, and strong hydrazine nucleophilicity.

Funder

Nanjing Tech University

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/NJ/D3NJ01643A

Reference25 articles.

1. S. A.Lawrence , Amines: Synthesis, Properties and Applications , Cambridge University Press , Cambridge, United Kingdom , 2004

2. A.Ricci , Amino Group Chemistry: From Synthesis to the Life Sciences , Wiley-VCH , Weinheim, Germany , 2008

3. Reductive Amination in the Synthesis of Pharmaceuticals

4. Biobased Amines: From Synthesis to Polymers; Present and Future

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