White light emission with unity efficiency from Cs2Na1−xAgxIn1−yBiyCl6 double perovskites: the role of bismuth and silver

Author:

Liu Fang1,Simbula Angelica1ORCID,Lai Stefano1,Wu Luyan1,Wang Qingqian2,Marongiu Daniela1ORCID,Pau Riccardo13,Matta Selene1,Pitzalis Federico1,Geddo Lehmann Alessandra1,Wang Kai2ORCID,Filippetti Alessio14ORCID,Quochi Francesco1ORCID,Saba Michele1ORCID,Mura Andrea1,Bongiovanni Giovanni1ORCID

Affiliation:

1. Dipartimento di Fisica, Università degli Studi di Cagliari, Monserrato (CA), I-09042, Italy

2. Department of Electrical and Electronic Engineering, Southern University of Science and Technology, Shenzhen, 518055, China

3. Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 09747 AG Groningen, The Netherlands

4. Istituto Officina dei Materiali (CNR-IOM) Cagliari, Monserrato (CA), I-09042, Italy

Abstract

Lead-free double perovskites are ideal lighting materials, capable of white light emission with unity efficiency. We demonstrate that the key ingredients for efficient emission are bismuth and silver with at least 0.1% fraction each.

Funder

European Social Fund

Regione Autonoma della Sardegna

Ministero dell'Università e della Ricerca

Fondazione di Sardegna

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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