Managing the retro-pathway in direct catalytic asymmetric aldol reactions of thioamides
Author:
Affiliation:
1. Institute of Microbial Chemistry (BIKAKEN), Tokyo
2. Tokyo 141-0021
3. Japan
4. JST
5. ACT-C
Abstract
Thioamides are the preferred pronucleophiles for direct catalytic asymmetric aldol reactions in the context of soft Lewis acid/hard Brønsted base cooperative catalysis.
Funder
Japan Society for the Promotion of Science
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC02218E
Reference47 articles.
1. Direkte katalytische asymmetrische Aldolreaktionen von Aldehyden mit nicht modifizierten Ketonen
2. Direct Catalytic Asymmetric Aldol Reaction
3. Proline-Catalyzed Direct Asymmetric Aldol Reactions
4. A Direct Catalytic Enantioselective Aldol Reaction via a Novel Catalyst Design
5. The Direct Catalytic Asymmetric Aldol Reaction
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