Exploring the mechanism of Grignard metathesis polymerization of 3-alkylthiophenes-Reference-Cited by-同舟云学术

Exploring the mechanism of Grignard metathesis polymerization of 3-alkylthiophenes

Published:2014 Issue:40 Volume:43 Page:15143-15150
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Bahri-Laleh Naeimeh¹²³,Poater Albert⁴⁵⁶,Cavallo Luigi⁷⁸⁹,Mirmohammadi Seyed Amin¹²³¹⁰¹¹

Affiliation:

1. Department of Polymerization Engineering

2. Iran Polymer and Petrochemical Institute

3. Tehran, Iran

4. Institut de Química Computacional i Catàlisi and Departament de Química

5. Universitat de Girona

6. 17071 Girona, Spain

7. Department of Chemistry and Biology

8. University of Salerno

9. Fisciano I-84084, Italy

10. Department of Polymer and Petrochemicals

11. Standard Research Institute

Abstract

In this study we have investigated computationally the mechanism of polymerization of 2,5-dibromo 3-butylthiophene via the GRIM method, with the focus on the origin of the head to tail (HT) selectivity.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT01617C

Reference27 articles.

1. Chain-Growth Polymerization for Poly(3-hexylthiophene) with a Defined Molecular Weight and a Low Polydispersity

2. Best of Both Worlds: Conjugated Polymers Exhibiting Good Photovoltaic Behavior and High Tensile Elasticity

3. Effect of the Side-Chain-Distribution Density on the Single-Conjugated-Polymer-Chain Conformation

4. Effect of Backbone Regioregularity on the Structure and Orientation of a Donor–Acceptor Semiconducting Copolymer

5. Regiocontrolled synthesis of poly(3-alkylthiophene)s by Grignard metathesis

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