A cobalt(ii) coordination polymer-derived catalyst engineered via temperature-induced semi-reversible single-crystal-to-single-crystal (SCSC) dehydration for efficient liquid-phase epoxidation of olefins

Author:

Hulushe Siya T.1ORCID,Watkins Gareth M.1,Khanye Setshaba D.2ORCID

Affiliation:

1. Department of Chemistry, Rhodes University, Makhanda 6139, South Africa

2. Division of Pharmaceutical Chemistry, Faculty of Pharmacy, Rhodes University, Makhanda 6139, South Africa

Abstract

Temperature-induced SCSC dehydration-rehydration processes between two 3D hybrid networks via solid phase intermediate transition were performed, with the new hydrated phase exhibiting superior catalytic performance in the epoxidation of olefins.

Funder

National Research Foundation

Atlantic Philanthropies

Rhodes University

Publisher

Royal Society of Chemistry (RSC)

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