Molecular recognition of upper rim functionalized cavitand and its unique dimeric capsule in the solid state

Author:

Kobayashi Mutsumi12345,Takatsuka Mei12345,Sekiya Ryo12345,Haino Takeharu12345

Affiliation:

1. Department of Chemistry

2. Graduate School of Science

3. Hiroshima University

4. Higashi-Hiroshima

5. Japan

Abstract

Calix[4]resorcinarene-based cavitand recognized the methyl group of the guests to form 1 : 1 host–guest complexes. In the solid state, the cavitand formed a dimeric capsule in which two molecules of nitromethane were entrapped by weak noncovalent interactions.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference44 articles.

1. D. J. Cram and J. M.Cram, Container Molecules and Their Guests, Royal Society of Chemistry, Cambridge, UK, 1994

2. C. D. Gutsche , Calixarene: An Introduction, Royal Society of Chemistry, Cambridge, UK, 2008

3. J. W. Steed and J. L.Atwood, Supramolecular Chemistry, A John Wiley and Sons, 2009

4. Host-guest complexation. 46. Cavitands as open molecular vessels form solvates

5. Measuring H-bonding in supramolecular complexes by gas phase ion–molecule reactions

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