Insights into the crucial role of a Zn promoter for methanol dehydrogenation to methyl formate over Cu(111) catalysts-Reference-Cited by-同舟云学术

Insights into the crucial role of a Zn promoter for methanol dehydrogenation to methyl formate over Cu(111) catalysts

Published:2022 Issue:37 Volume:24 Page:22661-22669
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Wu Shiping¹²,Sun Wei¹²,Wang Xuhui³,Zhao Jinxian¹²,Li Yan¹²,Quan Yanhong¹²,Ren Jun¹²^ORCID

Affiliation:

1. State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan University of Technology, No. 79 Yingze West Street, Taiyuan, 030024, China

2. Key Laboratory of Coal Science and Technology Taiyuan University of Technology, Ministry of Education, China

3. School of Electric Power, Civil Engineering and Architecture, Shanxi University, Taiyuan, 030013, China

Abstract

It can be concluded that the addition of a Zn promoter not only changed the reaction path of methanol dehydrogenation, but also reduced the energy barrier of the rate determining step and blocked the formation of the by-product CO effectively.

Funder

National Natural Science Foundation of China

Shanxi Provincial Key Research and Development Project

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP01544G

Reference56 articles.

1. Chemicals from Methanol

2. Methanol to Olefins (MTO): From Fundamentals to Commercialization

3. New methyl formate synthesis method: Coal to methyl formate

4. Dehydrogenation of methanol to methyl formate over copper catalysts

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